Product ID:SS-33-ON COMPOUND
MSDS Date:01/01/1987
FSC:6810
NIIN:00N008488
MSDS Number: BCQKL

MADISON CHEMICAL CO.,INC.

Emergency Phone: 812-273-6000,WK DAY

Cage: 60142

MADISON CHEMICAL CO INC

125 MADISON, IN 47250 US

Cage: 60142

METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III)

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 99%

OSHA PEL 350 PPM/450 STEL

ACGIH TLV: 350 PPM/450STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

Effects of Overexposure:INHALATN:DROWSINESS,HEADACHE,NAUSEA. IRRITATN
TO SKIN,EYE,MUCOUS MEMBRANES. HARMFUL/FATAL IF SWALLOW

First Aid:INHALATION:FRESH AIR,REST. SEEK MEDICAL ASSISTANCE. SKIN
CONTACT:WASH THOROUGHLY W/MILD SOAP & WATER. EYE CONTACT:FLUSH
W/COOL WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGESTION:CALL A PH YSICIAN IMMEDIATELY.

Flash Point:NONE
Extinguishing Media:WATER,DRY CHEMICAL,CARBON DIOXIDE
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE CLOTHING-FPN
Unusual Fire/Explosion Hazard:AT EXTREME HIGH TEMPS-AS IN WELDING-POTL
HARMFUL DECOMP PRODUCTS ARE FORMED;MAY INCLUDE HCL&PHOSGENE

Spill Release Procedures:ABSORB ON DRYING COMPOUND (FULLER'S
EARTH,SAWDUST,ETC.). VENTILATE AREA.

Handling and Storage Precautions:ALUMINUM,MAGNESIUM OR THEIR ALLOYS ARE
NOT RECM FOR STORAGE TANKS.STORE IN COOL PLACE.KEEP BUNG TIGHTLY
CLOSED.DONT FLAME CUT,BRAZE,WELD IN VICINITY.
Other Precautions:FOR INDUSTRIAL USE ONLY. NO SMOKING IN AREA OF USE;
DONT USE IN GENERAL VICINITY OF ARC WELDING,OPEN FLAMES,HOT
SURFACES;HEAT & /OR UV RADIATION MAY CAUSE FORMATION OF HCL &/OR
PHOSGENE

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATORY PROTECTION IN
ABSENCE (SEE SUPP DATA
Ventilation:LOCAL EXHAUST-FLOOR LEVEL VENT.GENERAL MECHANICAL-DOWN
DRAFT
Protective Gloves:NEOPRENE
Eye Protection:CHEMICAL WORKERS GOGGLES
Supplemental Safety and Health
EMER PHONE #;812-2736213,EVENING&WEEKEND. HAZARD DECOMP PRODUCTS:OF
CHLORINATED HYDROCARBONS. RESPIRATORY PROTECT:OF PROPER ENVIRON
CTRL.FOR EMERGENCY,NIOSH/MSHA APVD SCBA. DATE OF PREP:9/1/84

Boiling Pt:B.P. Text:165F,73.9C
Vapor Pres:120
Vapor Density:4.6
Spec Gravity:1.30
Evaporation Rate & Reference:0.35 (ETHYL ETHER)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:WATER-WHITE LIQUID W/CHLORINATED HYDROCARBON ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS,STRONG ALKALIES,ALUMINUM FINES.
Stability Condition to Avoid:OPEN FLAMES,ELECTRIC ARCS OR TEMPERATURES
ABOVE 1300F (704C)
Hazardous Decomposition Products:HCL,COCL*2 (PHOSGENE) &RELATED DECOMP
PRODUCTS (SEE SUPP DAT

Waste Disposal Methods:AS FOR ALL LOCAL,STATE & FEDERAL REGULATIONS
REGARDING CHLORINATED HYDROCARBONS. DO NOT DISCHARGE LARGE AMOUNT
TO DRAIN.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.